JPS6249582B2 - - Google Patents
Info
- Publication number
- JPS6249582B2 JPS6249582B2 JP55034821A JP3482180A JPS6249582B2 JP S6249582 B2 JPS6249582 B2 JP S6249582B2 JP 55034821 A JP55034821 A JP 55034821A JP 3482180 A JP3482180 A JP 3482180A JP S6249582 B2 JPS6249582 B2 JP S6249582B2
- Authority
- JP
- Japan
- Prior art keywords
- suspension
- gas
- electrode
- solid electrolyte
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000725 suspension Substances 0.000 claims description 52
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 34
- 239000007789 gas Substances 0.000 claims description 33
- 239000000843 powder Substances 0.000 claims description 31
- 239000007784 solid electrolyte Substances 0.000 claims description 18
- 229910052697 platinum Inorganic materials 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 16
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- 229910010293 ceramic material Inorganic materials 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- 229910000510 noble metal Inorganic materials 0.000 claims description 8
- 239000010970 precious metal Substances 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000011241 protective layer Substances 0.000 claims description 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052788 barium Inorganic materials 0.000 claims description 4
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 4
- 238000002485 combustion reaction Methods 0.000 claims description 4
- 230000007423 decrease Effects 0.000 claims description 4
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 3
- 239000005368 silicate glass Substances 0.000 claims description 3
- 238000005245 sintering Methods 0.000 claims description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 5
- 238000002848 electrochemical method Methods 0.000 claims 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
- 230000003247 decreasing effect Effects 0.000 claims 2
- 229910052759 nickel Inorganic materials 0.000 claims 2
- 229910052596 spinel Inorganic materials 0.000 claims 2
- 239000011029 spinel Substances 0.000 claims 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- 229910000990 Ni alloy Inorganic materials 0.000 claims 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- 229910001260 Pt alloy Inorganic materials 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
- 229910052703 rhodium Inorganic materials 0.000 claims 1
- 239000010948 rhodium Substances 0.000 claims 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 239000004408 titanium dioxide Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 description 18
- 239000004020 conductor Substances 0.000 description 4
- 239000007900 aqueous suspension Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4077—Means for protecting the electrolyte or the electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1213—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
- H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
- H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9033—Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9041—Metals or alloys
- H01M4/905—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9041—Metals or alloys
- H01M4/905—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9066—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC of metal-ceramic composites or mixtures, e.g. cermets
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biochemistry (AREA)
- Pathology (AREA)
- Analytical Chemistry (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- General Chemical & Material Sciences (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2911042A DE2911042C2 (de) | 1979-03-21 | 1979-03-21 | Elektrochemischer Meßfühler für die Bestimmung der Sauerstoffkonzentration und Verfahren zu seiner Herstellung |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS55128149A JPS55128149A (en) | 1980-10-03 |
JPS6249582B2 true JPS6249582B2 (en]) | 1987-10-20 |
Family
ID=6065991
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3482180A Granted JPS55128149A (en) | 1979-03-21 | 1980-03-21 | Electrochemical measuring sensor for oxygen concentration measurement in gas and producing same |
Country Status (3)
Country | Link |
---|---|
US (1) | US4280890A (en]) |
JP (1) | JPS55128149A (en]) |
DE (1) | DE2911042C2 (en]) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03248913A (ja) * | 1990-02-27 | 1991-11-06 | Nissan Motor Co Ltd | 自動車用ドアヒンジの取付構造 |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56160653A (en) * | 1980-05-14 | 1981-12-10 | Ngk Spark Plug Co Ltd | Manufacture of oxygen concentration cell |
EP0062330A1 (de) * | 1981-04-03 | 1982-10-13 | Fuji Electric Co., Ltd. | Sauerstoffempfindlicher Sensor mit einem Sensorelement aus Zirkonoxyd, Verfahren zu dessen Herstellung und Nachbehandlung, Verwendung des Sensors zur Messung in schwefeloxydhaltiger Messgasatmosphäre |
DE3128738A1 (de) * | 1981-07-21 | 1983-02-10 | Bbc Brown Boveri & Cie | "elektrochemische messzelle" |
JPS58109846A (ja) * | 1981-12-24 | 1983-06-30 | Toyota Motor Corp | 酸素検出用素子及びその製造方法 |
DE3219870A1 (de) * | 1982-05-27 | 1983-12-01 | Koertvelyessy Laszlo | Hochtemperatur-sauerstoffsonde |
JPS6036950A (ja) * | 1983-08-09 | 1985-02-26 | Ngk Insulators Ltd | 電気化学的セル及びその製造法 |
EP0281555A4 (en) * | 1985-10-29 | 1989-09-04 | Commw Scient Ind Res Org | COMPOSITE ELECTRODES FOR USE IN FIXED ELECTROLYTE DEVICES. |
AU607405B2 (en) * | 1985-10-29 | 1991-03-07 | Commonwealth Scientific And Industrial Research Organisation | Composite electrodes for use in solid electrolyte devices |
JPH0623725B2 (ja) * | 1985-12-25 | 1994-03-30 | 日本特殊陶業株式会社 | ガスセンサの調整法 |
JPS63218852A (ja) * | 1987-03-09 | 1988-09-12 | Yokogawa Electric Corp | 排ガス中のo↓2及び可燃ガス濃度測定装置 |
US5538612A (en) * | 1987-12-09 | 1996-07-23 | Ngk Spark Plug Co., Ltd. | Oxygen sensor element |
EP0369238B1 (en) * | 1988-11-01 | 1996-09-04 | Ngk Spark Plug Co., Ltd | Oxygen sensor and method for producing same |
JP2514701B2 (ja) * | 1988-12-02 | 1996-07-10 | 日本特殊陶業株式会社 | 酸素センサ |
US5139829A (en) * | 1988-12-22 | 1992-08-18 | Ngk Spark Plug Co., Ltd. | Method for producing oxygen detection element |
JP5336685B2 (ja) * | 1999-10-08 | 2013-11-06 | ヴァーサ パワー システムズ リミテッド | 固体電気化学的装置のための複合電極 |
CN111505079A (zh) * | 2019-01-31 | 2020-08-07 | 苏州工业园区传世汽车电子有限公司 | 一种具有优良性能的管式传感元件及其制备方法 |
CN111530474A (zh) * | 2020-06-23 | 2020-08-14 | 中国科学院长春应用化学研究所 | 一种贵金属单原子调控尖晶石阵列催化剂及其制备方法和应用 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3978006A (en) * | 1972-02-10 | 1976-08-31 | Robert Bosch G.M.B.H. | Methods for producing oxygen-sensing element, particularly for use with internal combustion engine exhaust emission analysis |
US4021326A (en) * | 1972-06-02 | 1977-05-03 | Robert Bosch G.M.B.H. | Electro-chemical sensor |
US3843400A (en) * | 1972-09-18 | 1974-10-22 | Westinghouse Electric Corp | Solid electrolyte cell |
JPS51145390A (en) * | 1975-06-10 | 1976-12-14 | Nissan Motor Co Ltd | Manufacturing method of a coated layer of oxygen senser |
JPS5210193A (en) * | 1975-07-15 | 1977-01-26 | Hitachi Ltd | Element for oxygen concentration measuring use |
JPS53100890A (en) * | 1977-02-16 | 1978-09-02 | Ngk Insulators Ltd | Oxygen concentration cell and its manufacture |
US4080276A (en) * | 1977-04-25 | 1978-03-21 | Bendix Autolite Corporation | Gas sensor with protective coating and method of forming same |
-
1979
- 1979-03-21 DE DE2911042A patent/DE2911042C2/de not_active Expired
-
1980
- 1980-03-14 US US06/130,453 patent/US4280890A/en not_active Expired - Lifetime
- 1980-03-21 JP JP3482180A patent/JPS55128149A/ja active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03248913A (ja) * | 1990-02-27 | 1991-11-06 | Nissan Motor Co Ltd | 自動車用ドアヒンジの取付構造 |
Also Published As
Publication number | Publication date |
---|---|
US4280890A (en) | 1981-07-28 |
JPS55128149A (en) | 1980-10-03 |
DE2911042A1 (de) | 1980-10-02 |
DE2911042C2 (de) | 1985-10-31 |
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